Magnetic and geometric anisotropy in particle-crosslinked ferrohydrogels
Literature Information
Lisa Roeder, Philipp Bender, Matthias Kundt, Andreas Tschöpe, Annette M. Schmidt
Particle-crosslinked polymer composites and gels have recently been shown to possess novel or improved properties due to a covalent particle–matrix interaction. We employ spindle-like hematite particles as exclusive crosslinkers in poly(acrylamide) gels, and exploit their extraordinary magnetic properties for the realization of ferrohydrogels with a perpendicular orientation of the preferred magnetic and geometric axes of the particles. The angle-dependent magnetic properties of uniaxially oriented gels are investigated and interpreted with respect to particle–matrix interactions. The impact of the particle orientation on the resulting angle-dependent magnetic performance reveals the presence of two different contributions to the magnetization: a hysteretic component ascribed to immobilized particles, and a pseudo-superparamagnetic, non-hysteretic component due to residual particle mobility. Furthermore, a plastic reorientation of magnetic particles in the matrix when subjected to a transversal field component is observed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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