A novel photoelectrochemical flow cell with online mass spectrometric detection: oxidation of formic acid on a nanocrystalline TiO2 electrode

Literature Information

Publication Date 2014-10-03
DOI 10.1039/C4CP03320E
Impact Factor 3.676
Authors

Robert Reichert, Zenonas Jusys, R. Jürgen Behm


View Original

Abstract

A novel thin-layer photoelectrochemical flow cell allowing the online mass spectrometric detection of volatile reaction products during photoelectrocatalytic reactions has been developed and applied for separating the contributions from photoelectrochemical water splitting and photoelectrooxidation of formic acid to the overall photocurrent in formic acid containing aqueous solution, using a nanocrystalline TiO2 (P25) thin-film electrode. The data reveal a clear suppression of the water oxidation reaction to O2 in the presence of formic acid. Advantages of this flow cell design over conventional photoelectrochemical cells with stagnant electrolyte in terms of mass transport will be demonstrated and discussed.

Related Literature

Correction: Strong enhancement of parity violation effects in chiral uranium compounds

Michael Wormit, Małgorzata Olejniczak, Anna-Lena Deppenmeier, Trond Saue, Peter Schwerdtfeger

2014-10-28 Correction

DOI: 10.1039/C4CP90164A

The influence of charge on the structure and dynamics of water encapsulated in reverse micelles

Animesh Patra, Trung Quan Luong, Rajib Kumar Mitra, Martina Havenith

2014-05-12 Paper

DOI: 10.1039/C4CP00386A

Describing the light intensity dependence of polymer:fullerene solar cells using an adapted Shockley diode model

L. H. Slooff, J. M. Kroon, W. Verhees, L. J. A. Koster, Y. Galagan

2014-01-27 Paper

DOI: 10.1039/C3CP55293D

Inside front cover

Cover

DOI: 10.1039/C4CP90071E

Why the photocatalytic activity of Mo-doped BiVO4 is enhanced: a comprehensive density functional study

Kaining Ding, Bin Chen, Zhenxing Fang, Zhongfang Chen

2014-05-20 Paper

DOI: 10.1039/C4CP01350F

Probing the microenvironment of unimicelles constituted of amphiphilic hyperbranched polyethyleneimine using 1-methyl-8-oxyquinolinium betaine

Agustín S. Picco, Gustavo F. Silbestri, R. Darío Falcone, Omar Azzaroni, Marcelo Ceolín, N. Mariano Correa

2014-05-19 Paper

DOI: 10.1039/C4CP01333F

Electron driven reactions in sulphur containing analogues of uracil: the case of 2-thiouracil

J. Kopyra, H. Abdoul-Carime, F. Kossoski, M. T. do N. Varella

2014-10-14 Paper

DOI: 10.1039/C4CP03544E

Diastereomeric preference of a triply axial chiral binaphthyl based molecule: a concentration dependent study by chiroptical spectroscopies

Zahra Dezhahang, Mohammad Reza Poopari, Florencio Eloy Hernández, Carlos Diaz, Yunjie Xu

2014-05-08 Paper

DOI: 10.1039/C4CP01704H

Sodium uptake in cell construction and subsequent in operando electrode behaviour of Prussian blue analogues, Fe[Fe(CN)6]1−x·yH2O and FeCo(CN)6

James C. Pramudita, Siegbert Schmid, Thomas Godfrey, Thomas Whittle, Moshiul Alam, Tracey Hanley, Helen E. A. Brand, Neeraj Sharma

2014-07-23 Paper

DOI: 10.1039/C4CP02676D

Inside front cover

Cover

DOI: 10.1039/C4CP90159B

You might also like

Compound Q&A

What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?

Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...

10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A

How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?

Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...

34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A

How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?

Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...

858-46-82,4,6-Tris(pentafluo...
Compound Q&A

What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?

When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...

56787-36-1Chloroac-nle-oh
Compound Q&A

What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?

Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...

752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A

Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?

Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...

55095-15-3alpha-(2-Bromophenyl...
Compound Q&A

How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?

Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...

139585-48-12-Chloro-5-methoxypy...
Compound Q&A

What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?

1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...

5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A

Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?

There are alternative reagents and compounds that can be used in the synthesis o...

903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A

What is Tungsten(IV) oxide (CAS: 12036-22-5)?

Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...

12036-22-5Tungsten(IV) oxide

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.