Low-energy vibrational spectra of flexible diphenyl molecules: biphenyl, diphenylmethane, bibenzyl and 2-, 3- and 4-phenyltoluene

Literature Information

Publication Date 2014-09-02
DOI 10.1039/C4CP03278K
Impact Factor 3.676
Authors

C. Falvo, P. Parneix, A. Gamboa, F. Calvo, Ph. Bréchignac


View Original

Abstract

Gas phase absorption far-infrared (FIR) spectra of six flexible hydrocarbon molecules containing two phenyl groups –biphenyl, diphenylmethane, bibenzyl and 2-, 3-, 4-phenyltoluene– are reported for the first time, allowing an accurate determination of most of their active low-frequency vibrational modes. DFT calculations have been carried out at the harmonic and perturbative anharmonic levels to predict the vibrational spectra of these molecules and unambiguously assign observed vibrational modes.

Related Literature

The elusive phosphorescence of pyrromethene–BF2 dyes revealed in new multicomponent species containing Ru(ii)–terpyridine subunits

Maurilio Galletta, Sebastiano Campagna, Manuel Quesada, Gilles Ulrich, Raymond Ziessel

2005-07-26 Communication

DOI: 10.1039/B507196H

Synthesis of 1,3-dioxo-hexahydropyrido[1,2-c][1,3]diazepine carboxylates, a new bicyclic skeleton formed by ring expansion–RCM methodology

Nicolai Dieltiens, Diederica D. Claeys, Bart Allaert, Francis Verpoort, Christian V. Stevens

2005-08-04 Communication

DOI: 10.1039/B508663A

Injectable biodegradable hydrogels composed of hyaluronic acid–tyramine conjugates for drug delivery and tissue engineering

Motoichi Kurisawa, Joo Eun Chung, Yi Yan Yang, Shu Jun Gao, Hiroshi Uyama

2005-07-28 Communication

DOI: 10.1039/B506989K

Organogel of an 8-quinolinol platinum(ii) chelate derivative and its efficient phosphorescence emission effected by inhibition of dioxygen quenching

Michihiro Shirakawa, Norifumi Fujita, Takahiro Tani, Kenji Kaneko, Seiji Shinkai

2005-07-04 Communication

DOI: 10.1039/B506148B

Evidence of carbon–carbon bond formation on GaAs(100) via Fischer–Tropsch methyleneinsertion reaction mechanism

Neil T. Kemp, Nagindar K. Singh

2005-08-02 Communication

DOI: 10.1039/B506195D

Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution

Yvonne Chiang, A. Jerry Kresge, Ikenna Onyido, John P. Richard, Peter Wan, Musheng Xu

2005-07-27 Communication

DOI: 10.1039/B506706E

Click-chemistry as an efficient synthetic tool for the preparation of novel conjugated polymers

Dirk Jan V. C. van Steenis, Olivier R. P. David, Gino P. F. van Strijdonck, Jan H. van Maarseveen, Joost N. H. Reek

2005-07-19 Communication

DOI: 10.1039/B507776A

In situ formation of ligandandcatalyst—application in ruthenium-catalyzed enantioselective reduction of ketones

Patrik Västilä, Jenny Wettergren, Hans Adolfsson

2005-07-12 Communication

DOI: 10.1039/B505516D

Silylstannations of α,β-unsaturated carbonyl compoundsvia the generation of Bu3Sn− in ionic liquids

Steven Dickson, Darrell Dean, Robert. D. Singer

2005-08-04 Communication

DOI: 10.1039/B508400H

Dendritic supramolecular assemblies for drug delivery

Meredith T. Morgan, Michael A. Carnahan, Stella Finkelstein, Carla A. H. Prata, Lovorka Degoricija, Stephen J. Lee, Mark W. Grinstaff

2005-07-14 Communication

DOI: 10.1039/B502411K

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.