Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution
Literature Information
Yvonne Chiang, A. Jerry Kresge, Ikenna Onyido, John P. Richard, Peter Wan, Musheng Xu
Photodecarboxylation of p-benzoylphenylacetic acid in aqueous solution produces the elongated enol 5, whose strength as an oxygen acid (pQEa = 7.67) makes it more acidic than simple enol analogs by several orders of magnitude.
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