Molecular brass: Cu4Zn4, a ligand protected superatom cluster

Literature Information

Publication Date 2014-06-19
DOI 10.1039/C4CC03401E
Impact Factor 6.222
Authors

Kerstin Freitag, Hung Banh, Christian Gemel, Rüdiger W. Seidel, Samia Kahlal, Jean-Yves Saillard, Roland A. Fischer


View Original

Abstract

The first example of ligand protected Cu–Zn clusters is described. Reaction of [CpCu(CNtBu)] with [Zn2Cp*2] yields [(CuCNtBu)4(ZnCp*)4] (1a) and [(CuCNtBu)4(ZnCp*)3(ZnCp)] (1b). According to DFT calculations, the [Cu4Zn4] unit fulfils the unified superatom model for cluster valence shell closing.

Related Literature

The electronic spectrum of C11 in its linear and cyclic conformation

Max Mühlhäuser, George E. Froudakis, Sigrid D. Peyerimhoff

2001-08-17 Paper

DOI: 10.1039/B103528M

Surface characterization of modified aluminas. Part 6. The poisonous effect of lead

Giuliana Magnacca, Claudio Morterra

2000-08-08 Paper

DOI: 10.1039/B004369I

Dynamic colloidal interactions between protein-stabilised particles—experiment and simulation

Herley Casanova, Jianshe Chen, Eric Dickinson, Brent S. Murray, Phillip V. Nelson, Martin Whittle

2000-08-09 Paper

DOI: 10.1039/B004023L

Highly conducting states in metal–ammonia solutions

Rainer Burkart, Ulrich Schindewolf

2000-06-14 Paper

DOI: 10.1039/B002598O

Theoretical study of the hydrogen abstraction reactions for CH3R + Cl → CH2R + HCl (R = Cl and Br)

Jing-Fa Xiao, Ze-Sheng Li, Yi-Hong Ding, Jing-Yao Liu, Xu-Ri Huang, Chia-Chung Sun

2001-08-29 Paper

DOI: 10.1039/B104667P

Anhydrous zirconium(IV) sulfate and tin(IV) sulfate: solid Lewis acid catalysts in liquid-phase hydro-acyloxy-addition reactions?

Ivo J. Dijs, Roene de Koning, John W. Geus, Leonardus W. Jenneskens

2001-09-12 Paper

DOI: 10.1039/B105049B

Comparison of the cross-sections and thermal rate constants for the reactions of C(3PJ) atoms with O2 and NO

Delphine Chastaing, Sébastien D. Le Picard, Ian R. Sims, Ian W. M. Smith

2000-06-16 Paper

DOI: 10.1039/B002583F

Evaporation after ionization in molecular clusters: application to 1-naphthol–(NH3)n

C. Dedonder-Lardeux, D. Grosswasser, C. Jouvet, S. Martrenchard, A. Teahu

2001-09-18 Paper

DOI: 10.1039/B104836H

You might also like

Compound Q&A

What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?

1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...

141290-59-71H-Indazole-6-carbon...
Compound Q&A

How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?

Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...

2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A

What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?

Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...

68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A

Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?

Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...

741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A

How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?

Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...

80714-39-22-Fluoro-6-hydrazino...
Compound Q&A

What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?

6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...

499214-11-86-Formyl-2-pyridinec...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A

How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?

9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...

29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A

How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?

1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...

1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A

How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?

Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...

671820-52-3Methyl 3-oxo-1,2,3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.