A facile and highly efficient strategy for esterification of poly(meth)acrylic acid with halogenated compounds at room temperature promoted by 1,1,3,3-tetramethylguanidine
Literature Information
Publication Date
2013-03-22
DOI
10.1039/C3PY00155E
Impact Factor
5.582
Authors
Qianbiao Li, Yinyin Bao, Hu Wang, Fanfan Du, Qing Li, Bangkun Jin, Ruke Bai
View Original
Abstract
Esterifications of poly(methacrylic acid) (PMAA) and poly(acrylic acid) (PAA) have been investigated with a wide variety of halogenated compounds such as iodide, bromide, and chloride using 1,1,3,3-tetramethylguanidine as a promoter. The results demonstrate that the poly(meth)acrylates can be obtained with an excellent degree of esterification at room temperature. The influence of solvent, reaction conditions, and halogenated compounds on the esterification reaction was examined. It was found that polar solvents, such as dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), are favorable for the esterification and high degree of esterification can be achieved in a short time. Moreover, the esterification reaction of PMAA has been successfully performed in an aqueous solution of DMSO, which indicates that the solvent does not necessarily have to be dried for this reaction. Primary and secondary halogenated compounds can successfully react with PMAA or PAA, while tertiary halogenated compounds fail to react. In addition, combining this esterification reaction with atom transfer radical polymerization (ATRP), macromonomers were conveniently prepared by the reaction of halogen-capped polymers with methacrylic acid under mild conditions.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
6-amino-1,3-dimethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione
CAS Number:
6642-31-5
Molecular Formula:
C6H9N3O2
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