An unprecedented intramolecular coupling of o-carboranyl and cyclopentadienyl. Synthesis and structural characterization of a ruthenium complex containing a novel doubly-bridged cyclopentadienyl-carboranyl ligand

Literature Information

Publication Date 2004-09-30
DOI 10.1039/B409772F
Impact Factor 6.222
Authors

Yi Sun, Hoi-Shan Chan, Pierre H. Dixneuf, Zuowei Xie


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Abstract

A novel ruthenium-mediated coupling reaction of a carboranyl with a cyclopentadienyl was discovered for the first time, leading to a brand new doubly-bridged cyclopentadienyl-carboranyl ligand bearing two five-membered rings and to a new type of chiral ruthenium complex.

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