Chemical recycling of the waste anodic electrolyte from the TiO2 nanotube preparation process to synthesize facet-controlled TiO2 single crystals as an efficient photocatalyst
Literature Information
Ai-Yong Zhang, Lu-Lu Long, Chang Liu, Wen-Wei Li, Han-Qing Yu
Anodization has been reported to be an effective electrochemical method to prepare vertically ordered, upright oriented TiO2 nanotubes for efficient photocatalysis, solar cells and many other fields. However, this process generates a large amount of residual anodic electrolytes that are rich in toxic fluorides, which are usually discarded and cause environmental contamination. Here, we propose a facile and effective method to prepare both pristine and N-doped TiO2 nanocrystals based on the recycling of waste ethylene glycol electrolyte from the widely-used anodic process. Under identical conditions, both the pristine and N-doped TiO2 nanocrystals exhibited nearly twice as high photocatalytic activity in decomposition of humic acids and bentazone than Degussa P25, one of the best commercial TiO2 photocatalysts. The preparation method had obvious economic and environmental benefits. The prepared TiO2 nanocrystals possessed superior photocatalytic degradation capacities for refractory pollutants, and could be used for efficient water treatment.
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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.












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