Chemical recycling of the waste anodic electrolyte from the TiO2 nanotube preparation process to synthesize facet-controlled TiO2 single crystals as an efficient photocatalyst

Literature Information

Publication Date 2014-02-24
DOI 10.1039/C3GC42167H
Impact Factor 10.182
Authors

Ai-Yong Zhang, Lu-Lu Long, Chang Liu, Wen-Wei Li, Han-Qing Yu


View Original

Abstract

Anodization has been reported to be an effective electrochemical method to prepare vertically ordered, upright oriented TiO2 nanotubes for efficient photocatalysis, solar cells and many other fields. However, this process generates a large amount of residual anodic electrolytes that are rich in toxic fluorides, which are usually discarded and cause environmental contamination. Here, we propose a facile and effective method to prepare both pristine and N-doped TiO2 nanocrystals based on the recycling of waste ethylene glycol electrolyte from the widely-used anodic process. Under identical conditions, both the pristine and N-doped TiO2 nanocrystals exhibited nearly twice as high photocatalytic activity in decomposition of humic acids and bentazone than Degussa P25, one of the best commercial TiO2 photocatalysts. The preparation method had obvious economic and environmental benefits. The prepared TiO2 nanocrystals possessed superior photocatalytic degradation capacities for refractory pollutants, and could be used for efficient water treatment.

Related Literature

A hybridization chain reaction coupled with gold nanoparticles for allergen gene detection in peanut, soybean and sesame DNAs

Dan Yuan, Yongxin Liu, Jilie Kong, Qin Chen

2019-04-30 Paper

DOI: 10.1039/C9AN00394K

Primer remodeling amplification-activated multisite-catalytic hairpin assembly enabling the concurrent formation of Y-shaped DNA nanotorches for the fluorescence assay of ochratoxin A

Jingfeng Wang, Yu Wang, Su Liu, Haiwang Wang, Xue Zhang, Xiaolei Song, Jinghua Yu

2019-04-01 Paper

DOI: 10.1039/C9AN00316A

Effect of energy per atom (E/n) on the Ar gas cluster ion beam (Ar-GCIB) and O2+ cosputter process

Shin-Kung Wang, Hsun-Yun Chang, Yi-Hsuan Chu, Wei-Lun Kao, Chen-Yi Wu, Yi-Wei Lee, Yun-Wen You, Kuo-Jui Chu, Shu-Hang Hung

2019-03-27 Paper

DOI: 10.1039/C8AN02452A

Highly sensitive and selective light-up fluorescent probe for monitoring gallium and chromium ions in vitro and in vivo

Xiaojun He, Chenglin Wu, Yuna Qian, Yahui Li, Lilei Zhang, Feng Ding, Hong Chen

2019-05-07 Paper

DOI: 10.1039/C9AN00625G

In situ study of RSK2 kinase activity in a single living cell by combining single molecule spectroscopy with activity-based probes

Shengrong Yu, Zhixue Du, Chaoqing Dong, Jicun Ren

2019-04-15 Paper

DOI: 10.1039/C9AN00178F

Synchrotron macro ATR-FTIR microspectroscopy for high-resolution chemical mapping of single cells

Jitraporn Vongsvivut, David Pérez-Guaita, Bayden R. Wood, Mark J. Tobin

2019-03-05 Paper

DOI: 10.1039/C8AN01543K

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Green Chemistry

Green Chemistry
CiteScore: 16.1
Self-citation Rate: 7.5%
Articles per Year: 944

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.