A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(i) complexes

Literature Information

Publication Date 2013-11-08
DOI 10.1039/C3GC42104J
Impact Factor 10.182
Authors

José G. Hernández, Neil A. J. Macdonald, Cristina Mottillo, Ian S. Butler, Tomislav Friščić


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Abstract

A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.

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