A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(i) complexes
Literature Information
José G. Hernández, Neil A. J. Macdonald, Cristina Mottillo, Ian S. Butler, Tomislav Friščić
A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.
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