Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

Literature Information

Publication Date 2014-01-30
DOI 10.1039/C3GC41855C
Impact Factor 10.182
Authors

Johannes Gross, Katharina Tauber, Michael Fuchs, Nina G. Schmidt, Aashrita Rajagopalan, Kurt Faber, Walter M. F. Fabian, Jan Pfeffer, Thomas Haas, Wolfgang Kroutil


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Abstract

The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.

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