Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase
Literature Information
Johannes Gross, Katharina Tauber, Michael Fuchs, Nina G. Schmidt, Aashrita Rajagopalan, Kurt Faber, Walter M. F. Fabian, Jan Pfeffer, Thomas Haas, Wolfgang Kroutil
The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.
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