Reclamation and reuse of ionic liquids from silica-based ionogels using spontaneous water-driven separation

Literature Information

Publication Date 2013-09-27
DOI 10.1039/C3GC41661E
Impact Factor 10.182
Authors

Ariel I. Horowitz, Yushi Wang, Matthew J. Panzer


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Abstract

Ionic liquids (ILs) are widely regarded as “green” materials, partially because they are assumed to be recyclable in most applications. Here, the effectiveness of a water-based IL reclamation process with low energy requirements is demonstrated using two types of silica-supported ionic liquid-based gel electrolytes (ionogels) incorporating a variety of common ionic liquids. More than 90% of the IL can be separated from the ionogel silica scaffold simply by submerging the ionogel in water, with no additional energy input. It is posited that water is able to compete with the hydrophobic IL for access to the hydrophilic silica scaffold surface, liberating the IL from the ionogel structure. Spontaneous water-based separation leads to the recovery of at least 70% of the original IL mass; transfer losses experienced at the laboratory scale are expected to decrease with process scale-up. Recovered ILs exhibit similar electrical performance to the virgin materials in a double layer capacitor structure.

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Green Chemistry

Green Chemistry
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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

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