Metal-free arylations via photochemical activation of the Ar–OSO2R bond in aryl nonaflates

Literature Information

Publication Date 2013-07-22
DOI 10.1039/C3GC41009A
Impact Factor 10.182
Authors

Carlotta Raviola, Veronica Canevari, Stefano Protti, Angelo Albini, Maurizio Fagnoni


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Abstract

The photolysis of electron-rich aryl nonaflates (ArONfs) in protic media was investigated and heterolysis of the Ar–OS bond (from 3ArONf) took place. The reaction generated a triplet phenyl cation that added to π-bond nucleophiles. This metal-free arylation method was made further useful by adopting in situ preparation of ArONf from the corresponding phenol.

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