Delayed electron–hole pair recombination in iron(iii)-oxo metal–organic frameworks
Literature Information
Katrien G. M. Laurier, Eduard Fron, Pedro Atienzar, Koen Kennes, Hermenegildo Garcia, Mark Van der Auweraer, Dirk E. De Vos, Johan Hofkens
The photodynamic properties of a series of Fe(III)-MOFs have been examined via redox reactions with N,N,N′,N′-tetramethyl-p-phenylenediamine as an electron donor and methyl viologen as an electron acceptor. Furthermore, photogeneration of long-lived species in MIL-88B(Fe) has been proven via transient absorption spectroscopy.
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