The interaction of H2O2 with TiAlPO-5 molecular sieves: probing the catalytic potential of framework substituted Ti ions

Literature Information

Publication Date 2013-05-03
DOI 10.1039/C3CP51214B
Impact Factor 3.676
Authors

Chiara Novara, Almudena Alfayate, Gloria Berlier, Sara Maurelli, Mario Chiesa


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Abstract

A combination of EPR, ENDOR and HYSCORE experiments has been used to investigate the reactivity of hydrogen peroxide with TiAlPO-5 materials under both hydrated and anhydrous conditions. Superoxide radical anions, generated upon reaction, are used as paramagnetic probes to investigate the nature and reactivity of framework incorporated Ti ions. Super hyperfine interactions with 27Al, 31P and 1H are resolved, which allow a detailed mapping of the local environment of the adsorbed O2− ions. Evidence is provided for the first time of a specific redox activity associated with Ti ions incorporated at framework Al sites of TiAlPO materials.

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Front cover

Cover

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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