Raman enhancement by plasmonic excitation of structurally-characterized metal clusters: Au8, Ag8, and Cu8
Literature Information
Tomokazu Yasuike, Katsuyuki Nobusada
The optical responses of metal clusters, M8 (M = Au, Ag and Cu), are investigated by the linear response theory based on the density functional theory. Unlike sodium clusters [Yasuike et al., Phys. Rev. A, 2011, 83, 013201], the plasmonic excitations in the present metal clusters are strongly reduced by the background d-electron excitations, i.e., Landau damping. To avoid the reduction of plasmon intensity, the control of cluster structures is one of the promising strategies. We demonstrate that the plasmonic excitations of the linear clusters are partially decoupled with the background d-electron excitations and their intensities are much stronger than those of the three-dimensional bicapped octahedral isomers. The linear isomer gives a strong enhancement of the Raman vibrational spectrum of a pyrazine molecule.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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