Syntheses, structures, and magnetic properties of a series of Mn-containing coordination polymers based on 5-nitro-1,2,3-benzenetricarboxylic acid and different N-donor ligands

Literature Information

Publication Date 2013-07-09
DOI 10.1039/C3CE40772A
Impact Factor 3.545
Authors

Yuting Yang, Changzheng Tu, Feixiang Cheng, Fan Wang


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Abstract

Three new 5-nitro-1,2,3-benzenetricarboxylic acid based complexes, [Mn7(nbta)4(Hnbta)(2,2′-bipy)4(H2O)8]·2H2O (1), [MnII3MnIII(nbta)3(bimb)1.5·H2O]·2H2O (2), [Mn3(nbta)2(bix)1.5(μ2-H2O)·(H2O)6]·2H2O (3) (H3nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, 2,2′-bipy = 2,2′-bipyridine, bimb = 1,1′-(1,4-butanediyl)bis(imidazole), bix = 1,4-bis(imidazol-1-ylmethyl)benzene), were hydrothermally synthesized. Complex 1 exhibits a 3D framework constructed from Mn4 cores, displaying the α-Po net with 41263 topology. Complexes 2 and 3 present a 2D network with multinuclear clusters as the linking nodes. All the complexes were suitably characterized by elemental analysis, FTIR spectra, thermogravimetric analysis and X-ray diffraction techniques. Moreover, direct current magnetic susceptibility measurements were carried out to study their magnetic properties.

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DOI: 10.1039/C6CP90164F

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CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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