Direct C–H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles

Literature Information

Publication Date 2012-10-24
DOI 10.1039/C2CY20505J
Impact Factor 6.119
Authors

Sergei I. Kozhushkov, Harish Kumar Potukuchi, Lutz Ackermann


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Abstract

Significant progress has been accomplished in direct C–H bond arylations of arenes and heteroarenes with readily accessible, inexpensive phenol derivatives. Thus, ruthenium biscarboxylate complexes and inexpensive cobalt compounds allowed for challenging C–H bond derivatizations of arenes. Further, palladium, nickel and cobalt catalysts set the stage for step-economical C–H/C–O bond functionalization with electron-rich as well as electron-deficient heteroarenes.

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Catalysis Science & Technology

Catalysis Science & Technology
CiteScore: 5.91
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