Generation of (nonafluoro-tert-butoxy)methyl ponytails for enhanced fluorous partition of aromatics and heterocycles

Literature Information

Publication Date 2012-01-16
DOI 10.1039/C2CP23113A
Impact Factor 3.676
Authors

Xi Zhao, Wing Yan Ng, Kai-Chung Lau, Alana E. C. Collis, István T. Horváth


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Abstract

The reaction of sodium perfluoro-tert-butoxide with benzylic carbon–bromide bond(s) leads to the formation of (nonafluoro-tert-butoxy)methyl ponytail(s), which can enhance the fluorous solubility and partition of aromatics and heterocycles.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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