A highly selective fluorescent probe for BO3− based on acetate derivatives of coumarin in aqueous solution and thimerosal
Literature Information
Publication Date
2012-11-19
DOI
10.1039/C2AN36492A
Impact Factor
4.616
Authors
Fangjun Huo, Long Wang, Yueyin Chu, Caixia Yin, Jianbin Chao, Yongbin Zhang, Xuxiu Yan, Anmin Zheng, Shuo Jin, Peng Zhi
View Original
Abstract
The acetate derivatives of coumarin exhibited a prominent turn-on type signaling behavior toward BO3− ions over other common anions. Signaling is based on the selective deprotection of acetate groups by perborate, which resulted in significant fluorogenic signaling in an acetate buffered solution (pH 5.0). Interestingly, the detection process makes the raw material of 7-hydroxycoumarin regenerate, and the probe could be applied for the detection of BO3− of thimerosal. Furthermore, the optical properties of the probe and its BO3−-induced product were theoretically studied based on density functional theory (DFT) and the time-dependent DFT (TDDFT) explored at the B3LYP/6-311+G (d, p) level.
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Source Journal
Analyst
CiteScore:
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Self-citation Rate:
5.6%
Articles per Year:
653
Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.
Recommended Compounds
4-(4-Chloro-2-methoxyphenyl)-3-fluorobenzoic acid
CAS Number:
1261970-23-3
Molecular Formula:
C14H10ClFO3
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