![7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/209/209984-32-7-9912.webp "7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1) structure")
7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1)
CAS Number:
209984-32-7
Molecular Formula:
C15H15ClN2O
Modular oxime functionalization of well-defined alkoxyamine-containing polymers
Literature Information
Publication Date
2011-11-07
DOI
10.1039/C1PY00451D
Impact Factor
5.582
Authors
Soma Mukherjee, Philip J. Costanzo
View Original
Abstract
Phthalamide-protected O-(4-vinylbenzyl)-hydroxylamine was polymerized via reversible addition-fragmentation chain transfer (RAFT) polymerization with good control of the polymer molecular weight and retention of chain end functionality. The resulting polymer was deprotected by cleavage of the phthalamido protecting groups via treatment with hydrazine to reveal the latent side-chain alkoxyamine functionality (R–O–NH2). The alkoxyamine polymer scaffold was coupled with model small molecule aldehydes and ketones via highly efficient “click” oxime bond formation. The ability of the coupling reactions to be conducted at a variety of temperatures, in the presence of oxygen, and without any additional reagents makes this an attractive modular strategy for preparing well-defined polymers with high degrees of functionality.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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