![Ethyl 2-[(3-bromo-4-pyridinyl)sulfanyl]-2-methylpropanoate structure](https://static.chemtradehub.com/structs/135/1352794-86-5-a8aa.webp "Ethyl 2-[(3-bromo-4-pyridinyl)sulfanyl]-2-methylpropanoate structure")
Ethyl 2-[(3-bromo-4-pyridinyl)sulfanyl]-2-methylpropanoate
CAS Number:
1352794-86-5
Molecular Formula:
C11H14BrNO2S
An isoindigo and dithieno[3,2-b:2′,3′-d]silole copolymer for polymer solar cells
Literature Information
Publication Date
2011-10-27
DOI
10.1039/C1PY00402F
Impact Factor
5.582
Authors
Romain Stalder, Caroline Grand, Jegadesan Subbiah, Franky So, John R. Reynolds
View Original
Abstract
The copolymer of isoindigo and dithieno[3,2-b:2′,3′-d]silole, P(iI-DTS), is reported as prepared by Stille coupling to yield a soluble high molecular weight material absorbing light throughout the visible spectrum up to 800 nm. With deep HOMO and LUMO energy levels (high ionization potential and electron affinity) electrochemically measured at −5.55 and −3.95 eV respectively, this new p-type polymer enabled the fabrication of high open circuit voltage polymer solar cells when blended with fullerene derivatives. By employing solvent additives, the morphology of the devices was optimized to yield power conversion efficiencies of 4%.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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