Copolymers of 2-hydroxyethylacrylate and 2-methoxyethyl acrylate by nitroxide mediated polymerization: kinetics, SEC-ESI-MS analysis and thermoresponsive properties
Literature Information
Publication Date
2011-09-27
DOI
10.1039/C1PY00344E
Impact Factor
5.582
Authors
Anna-Marie Zorn, Helmut Keul, Christopher Barner-Kowollik, Martin Moeller
View Original
Abstract
The nitroxide mediated copolymerization of 2-hydroxyethyl acrylate (HEA) and 2-methoxyethyl acrylate (MEA) is reported. The copolymerization kinetics followed the persistent radical model and revealed the formation of well-defined ideal random copolymers (rHEA = 0.93 ± 0.09; rMEA = 0.95 ± 0.09). SEC-ESI-MS proved the presence of both the initiation fragment and SG1 as chain ends of the polymers. The cloud point temperature of the copolymers increased from 5 °C and 60 °C with increasing HEA content from 0% to 70% and they are discussed in relation to both monomer and end-group structure.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
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Recommended Compounds
![Methyl 5-iodo-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-2-thiophenecarboxylate structure](https://static.chemtradehub.com/structs/100/1007171-35-8-177e.webp "Methyl 5-iodo-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-2-thiophenecarboxylate structure")
Methyl 5-iodo-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-2-thiophenecarboxylate
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