![2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid structure](https://static.chemtradehub.com/structs/473/473924-63-9-973b.webp "2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid structure")
2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid
CAS Number:
473924-63-9
Molecular Formula:
C12H16N2O4
Polymerization of 4-vinylpyridine and N,N-dimethylacrylamide using a system without organic initiator
Literature Information
Publication Date
2011-07-27
DOI
10.1039/C1PY00223F
Impact Factor
5.582
Authors
Sijing Xia, Bin Yang, Guangzhao Li, Xiaoqing Zhu, Anning Wang, Jin Zhu
View Original
Abstract
Polymerization of monomer 4-vinylpyridine (4VP) and N,N-dimethylacrylamide (DMAA) could be carried out using a system without organic initiator. It was found that metal catalyst (CuCl) and water played a vital role in this process through a series of control experiments. Polymers with high degrees of polymerization (Mp = 128739 for P4VP and Mp = 355122 for PDMAA) have been obtained by the addition of Au nanoparticles (AuNPs). Radical inhibitor and electron spin resonance (ESR) spin-trapping techniques have been used to analyze the polymerization process and identify the involvement of radicals in the reaction.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![(2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13
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,17-tetraen-21-yl]-2-methyl-2-butenoic acid structure")
(11alpha,13E)-11-Hydroxy-9,15-dioxoprost-13-en-1-oic acid
CAS Number:
22973-19-9
Molecular Formula:
C20H32O5
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