4-Cyclohexene-1,2-dicarboxylic acid, 1,2-dimethyl ester, (1R,2R)-rel-
CAS Number:
17673-68-6
Molecular Formula:
C10H14O4
Efficient dual radical/cationic photoinitiator under visible light: a new concept
Literature Information
Publication Date
2011-06-13
DOI
10.1039/C1PY00140J
Impact Factor
5.582
Authors
Jacques Lalevée, Nicolas Blanchard, Mohamad-Ali Tehfe, Mathieu Peter, Fabrice Morlet-Savary, Didier Gigmes, Jean Pierre Fouassier
View Original
Abstract
A new concept based on the photoredox catalysis is proposed for the design of a photoinitiating system able to efficiently generate, in a single catalytic cycle, both a radical and a cation as initiating species. This is exemplified here by the tris(1,10-phenanthroline)ruthenium(II) (Ru(phen)32+) complex in combination with a diphenyl iodonium salt and a silane. Interesting and promising photopolymerization profiles in free radical photopolymerization (FRP) and free radical promoted cationic photopolymerization (FRPCP) are obtained under air and upon xenon lamp exposure and even soft irradiation conditions (fluorescence bulb, sunlight). An acrylate/epoxide blend is also easily polymerized under air using a fluorescent bulb. The mechanisms are investigated by ESR and Laser Flash Photolysis experiments.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/871/871332-68-2-0e3b.webp "[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure")
[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid
CAS Number:
871332-68-2
Molecular Formula:
C11H15BClNO3
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