Charge transfer properties of Tröger base derivatives

Literature Information

Publication Date 2011-09-30
DOI 10.1039/C1CP22086A
Impact Factor 3.676
Authors

Cristina. L. Ramírez, César Pegoraro, Leandro Trupp, Andrea Bruttomesso, Valentín Amorebieta, D. Mariano A. Vera, Alejandro R. Parise


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Abstract

Two triarylamine centers bridged through an aliphatic bridge feature unexpected charge transfer properties, bearing an important electronic coupling between them in the absence of a π linker; EPR, electrochemistry, electronic spectroscopy and first principles molecular calculations are combined to study the electronic structure of this compound.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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