Initiation and control of catalytic surface reactions with shaped femtosecond laser pulses

Literature Information

Publication Date 2011-12-05
DOI 10.1039/C1CP21827A
Impact Factor 3.676
Authors

Daniel Wolpert, Horst Weiss, Gustav Gerber


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Abstract

We report on femtosecond laser-induced catalytic reactions of carbon monoxide and hydrogen on single crystal surfaces under high vacuum conditions. Several product molecules are synthesized, among them also species for whose formation at least three reactants are required. By applying closed-loop optimal control, we manipulate these reactions and selectively optimize the ratio of different bond-forming reaction channels, in contrast to previous quantum control experiments aiming at bond-cleavage. Further experiments explore the nontrivial control mechanism and its sensitivity to the relative proportion of the two reactant gases.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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