The structure of gas-phase [Al·nH2O]+: hydrated monovalent aluminium Al+(H2O)n or hydride-hydroxide HAlOH+(H2O)n−1?

Literature Information

Publication Date 2011-03-11
DOI 10.1039/C1CP00048A
Impact Factor 3.676
Authors

Christian van der Linde, Martin K. Beyer


View Original

Abstract

Theoretical studies predict that [Al·nH2O]+clusters are present as hydride-hydroxide species HAlOH+(H2O)n−1 in gas-phase experiments, energetically favoured by 200 kJ mol−1 over Al+(H2O)n. After collisions with D2O, however, no H/D scrambling occurs between H2O and D2O in clusters with n > 38, indicating that large clusters are present as the higher-energy isomers Al+(H2O)n.

Related Literature

Plasmon-enhanced homogeneous and heterogeneous triplet–triplet annihilation by gold nanoparticles

Xian Cao, Bo Hu, Rui Ding, Peng Zhang

2015-05-12 Communication

DOI: 10.1039/C5CP01876E

Chemical modifications and stability of phosphorene with impurities: a first principles study

D. W. Boukhvalov, A. N. Rudenko, D. A. Prishchenko, V. G. Mazurenko

2015-05-06 Paper

DOI: 10.1039/C5CP01901J

Co-solvent enhanced zinc oxysulfide buffer layers in Kesterite copper zinc tin selenide solar cells

K. Xerxes Steirer, Rebekah L. Garris, Jian V. Li, Michael J. Dzara, Paul F. Ndione, Kannan Ramanathan, Ingrid Repins, Glenn Teeter, Craig L. Perkins

2015-05-13 Paper

DOI: 10.1039/C5CP01607J

Gated electron transfer reactions of truncated hemoglobin from Bacillus subtilis differently orientated on SAM-modified electrodes

Deby Fapyane, Andrey Kartashov, Claes von Wachenfeldt, Elena E. Ferapontova

2015-05-06 Paper

DOI: 10.1039/C5CP00960J

Back cover

Cover

DOI: 10.1039/C5CP90100F

Strain induced crystallization and melting of natural rubber during dynamic cycles

Catherine Gauthier, Etienne Munch, Dominique Thiaudière

2015-05-08 Paper

DOI: 10.1039/C5CP00384A

Low-temperature VUV photoluminescence and thermoluminescence of UV excited afterglow phosphor Sr3AlxSi1−xO5:Ce3+,Ln3+ (Ln = Er, Nd, Sm, Dy and Tm)

Hongde Luo, Adrie J. J. Bos, Anna Dobrowolska, Pieter Dorenbos

2015-05-13 Paper

DOI: 10.1039/C5CP01710F

Crystallographic dependence of photocatalytic activity of WO3 thin films prepared by molecular beam epitaxy

Tamas Varga, Pengfei Yan, Zhiguo Wang, Chongmin Wang, Scott A. Chambers, Yingge Du

2015-05-11 Paper

DOI: 10.1039/C5CP01344E

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.