Formation and hydrogen release of hydrazine bisborane: transfer vs. attachment of a borane
Literature Information
Saartje Swinnen, Jerzy Leszczynski, Minh Tho Nguyen
The reactivity of hydrazine in the presence of diborane has been investigated using ab initio quantum chemical computations (MP2 and CCSD(T) methods with the aug-cc-pVTZ basis set). Portions of the relevant potential energy surface were constructed to probe the formation mechanism of the hydrazine diborane (BH3BH3NH2NH2) and hydrazine bisborane (BH3NH2NH2BH3). The differences between both adducts are established. The release of hydrogen molecules from hydrazine bisborane adducts has also been characterized. Our results suggest that the BH3NH2NH2BH3 adduct, which has been prepared experimentally, is formed from the starting reactants hydrazine + diborane. The observed adduct is produced by a transfer of a BH3 group from BH3BH3NH2NH2 rather than by the direct attachment of a separate BH3 group, generated by predissociation of diborane, to BH3NH2NH2.
Recommended Journals

Science

Israel Journal of Chemistry

Organic Preparations and Procedures International

Kinetics and Catalysis

Journal of Organometallic Chemistry

Planta Medica

Journal of Physics and Chemistry of Solids

Journal of Medicinal Chemistry

Proceedings of the National Academy of Sciences of the United States of America

Journal of Heterocyclic Chemistry
Related Literature
Binderless thin films of zeolite-templated carbon electrodes useful for electrochemical microcapacitors with ultrahigh rate performance
Ángel Berenguer-Murcia, Ramiro R. Ruiz-Rosas, Jaime García-Aguilar, Khanin Nueangnoraj, Hirotomo Nishihara, Emilia Morallón, Takashi Kyotani, Diego Cazorla-Amorós
DOI: 10.1039/C3CP51945G
Visible light-induced OH radicals in Ga2O3: an EPR study
Zeev Tzitrinovich, Anat Lipovsky, Aharon Gedanken, Rachel Lubart
DOI: 10.1039/C3CP00102D
Enhancement of electroluminescence in zirconium poly carboxylic acid-based light emitting diodes by bathophenanthroline ligand
Hashem Shahroosvand, Fahimeh Nasouti, Ahmad Sousaraei, Ezeddin Mohajerani, Amir Khabbazi
DOI: 10.1039/C3CP51141C
The detailed characterization of electrochemically switchable molecular assemblies on silicon electrodes
Simone Ciampi, Michael James, Moinul H. Choudhury, Nadim A. Darwish, J. Justin Gooding
DOI: 10.1039/C3CP50355K
Mechanism of one-electron oxidation of metformin in aqueous solution
C. Marchetti, R. Lazzaroni, D. Jore, M. Gardès-Albert
DOI: 10.1039/C3CP50602A
Electronic structure and morphology of dark oxides on zinc generated by electrochemical treatment
Paul Schneider, Bi-Ju Liu, Sergiy Borodin, Bin Ren, Andreas Erbe
DOI: 10.1039/C3CP44714F
Calculation of arrangement of oxygen ions and vacancies in double perovskite GdBaCo2O5+δ by first-principles DFT with Monte Carlo simulations
Hiromasa Shiiba, Toshihiro Kasuga, Robin W. Grimes, John A. Kilner
DOI: 10.1039/C3CP50316J
In situ surface-enhanced Raman spectroscopic study of formic acid electrooxidation on spontaneously deposited platinum on gold
Ranjani Muralidharan, Michael McIntosh, Xiao Li
DOI: 10.1039/C3CP51128F
The effect of the molecular structures of dicyanomethylene compounds on their supramolecular assembly, photophysical and electrochemical properties
Catiúcia R. M. O. Matos, Fabio S. Miranda, José W. de M. Carneiro, Carlos B. Pinheiro, Célia M. Ronconi
DOI: 10.1039/C3CP51957K
You might also like
How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?
Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...
What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?
5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...
What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?
(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...
How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?
Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...
What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?
When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...
What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?
Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...
Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?
(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...
What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?
Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...
Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?
2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...
How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?
3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

![4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine structure 4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine structure](https://static.chemtradehub.com/structs/120/1206594-08-2-7afb.webp)


![Imidazo[1,5-a]pyrazine structure Imidazo[1,5-a]pyrazine structure](https://static.chemtradehub.com/structs/274/274-49-7-d749.webp)