Compilation of all the isothermal mass/charge transport properties of the mixed conducting La2NiO4+δ at elevated temperatures
Literature Information
Hong-Seok Kim, Han-Ill Yoo
It is known [H.-S. Kim and H.-I. Yoo, Phys. Chem. Chem. Phys., DOI:10.1039/c0cp00722f] that all the isothermal mass and charge transport properties of a mixed ionic electronic conductor compound can be universally represented by a 2 × 2 Onsager transport coefficient matrix. Furthermore, the three independent coefficients of the matrix can be determined from a simple relaxation experiment under the ion-blocking condition in association with the equation of state with respect to the nonstoichiometry or thermodynamic factor. By using this method, we compile the transport matrices at 800 °C, 900 °C and 1000 °C, respectively, on the system of La2NiO4+δ across its entire stability range, and calculate thereby its transport properties to compare with the literature values available. The interference effect between mobile oxygen ions and holes upon their transfer is discussed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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