Single dibenzoterrylene molecules in naphthalene and 2,3-dimethylnaphthalene crystals: vibronic spectra
Literature Information
Irena Deperasińska, Elena Karpiuk, Marzena Banasiewicz, Artur Makarewicz, Bolesław Kozankiewicz
Fluorescence excitation spectra of single dibenzoterrylene (DBT) molecules embedded in naphthalene (N) and 2,3-dimethylnaphthalene (2,3-DMN) crystals were studied at 5 K. The frequencies characterizing the vibronic structure of single DBT molecules in an N crystal agree with the theoretical prediction for the isolated DBT molecule. The ‘dipolar’ disorder encountered in 2,3-DMN crystals leads to a broad distribution of frequencies of the (0,0) lines of single DBT molecules. Moreover, the observed vibronic frequencies and intensities in the spectrum of DBT in 2,3-DMN crystals are slightly different to those in an N crystal. We conclude that the structure of DBT molecules in a 2,3-DMN crystal is disturbed in comparison with isolated DBT and the main change concerns its central tetracene moiety.
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Physical Chemistry Chemical Physics

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