Direct formation of a 2D redox-active adlayer based on a bisterpyridine derivative and Co2+ on a Au(111)electrode

Literature Information

Publication Date 2010-09-24
DOI 10.1039/C0CP00981D
Impact Factor 3.676
Authors

Soichiro Yoshimoto, Yuta Ono, Katsuhiko Nishiyama, Isao Taniguchi


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Abstract

The direct assembly of single component 4′,4′′′′-(1,4-phenylene)bis(2,2′ : 6′,2′′-terpyridine) (PTPy) and Co2+ and PTPy mixed arrays was examined on a Au(111) surface by a simple immersion method. A redox active 2D adlayer consisting of a bisterpyridine derivative and cobalt ions was found to form directly on Au(111) from solution, suggesting that new nanostructures and/or adlayers with electrochemical activity can be precisely designed and controlled by selection of the metal ion and ligand.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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