Highly ordered aluminium-planted mesoporous silica as active catalyst for Biginelli reaction and formyl C–H insertion reaction with diazoester
Literature Information
Hiroaki Murata, Haruro Ishitani, Masakazu Iwamoto
Al-planted MCM-41s (Al-M41s) with regular mesoporous structure and Si/Al ratio of 23–32 were successfully prepared by the template-ion exchange method in which the template/Si molar ratio and Si/Al ratio were adjusted at 1.44 and 5–15, and showed much higher catalytic activity for the titled reactions than the other types of Al-M41s prepared by post-synthesis or sol–gel methods.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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