Aerobic oxidation of alcohols catalyzed by rhodium(iii) porphyrin complexes in water: reactivity and mechanistic studies

Literature Information

Publication Date 2010-08-12
DOI 10.1039/C0CC01406K
Impact Factor 6.222
Authors

Lianghui Liu, Mengmeng Yu, Bradford B. Wayland, Xuefeng Fu


View Original

Abstract

Selective oxidation of alcohol in water using molecular oxygen as the terminal oxidant is mediated by rhodium porphyrin complexes. Addition of methanol to an aqueous solution of (TSPP)Rh(III) resulted in observation of the key intermediate porphyrin rhodium(III) methoxide species. The activation parameters for βC–H elimination of Rh–alkoxide were evaluated.

Related Literature

The effect of molecular dynamics sampling on the calculated observable gas-phase structures

Arseniy A. Otlyotov

2016-06-07 Paper

DOI: 10.1039/C6CP02973F

Enhanced photoelectrochemical performance of quantum dot-sensitized TiO2 nanotube arrays with Al2O3 overcoating by atomic layer deposition

Min Zeng, Xiange Peng, Jianjun Liao, Guizhen Wang, Yanfang Li, Jianbao Li, Yong Qin, Joshua Wilson, Aimin Song

2016-04-15 Paper

DOI: 10.1039/C6CP01299J

An NMR study on the mechanisms of freezing and melting of water confined in spherically mesoporous silicas SBA-16

Tatsuya Miyatou, Ryutaro Ohashi, Tomonori Ida, Shigeharu Kittaka, Motohiro Mizuno

2016-06-15 Paper

DOI: 10.1039/C6CP03111K

Defect induced tunable near infrared emission of Er–CeO2 by heterovalent co-dopants

Mihaela Florea, Daniel Avram, Bogdan Cojocaru, Ion Tiseanu, Vasile Parvulescu, Carmen Tiseanu

2016-06-03 Paper

DOI: 10.1039/C6CP02754G

Methanol diffusion in zeolite HY: a combined quasielastic neutron scattering and molecular dynamics simulation study

Victoria García Sakai, Ian P. Silverwood, Nikolaos Dimitratos

2016-05-16 Paper

DOI: 10.1039/C6CP01151A

Structural phase transition in perovskite metal–formate frameworks: a Potts-type model with dipolar interactions

Mantas Šimėnas, Sergejus Balčiūnas, Mirosław Maçzka, Jūras Banys, Evaldas E. Tornau

2016-06-13 Paper

DOI: 10.1039/C6CP03414D

Correction: Gd(iii)–Gd(iii) EPR distance measurements – the range of accessible distances and the impact of zero field splitting

Arina Dalaloyan, Mian Qi, Sharon Ruthstein, Shimon Vega, Adelheid Godt, Akiva Feintuch, Daniella Goldfarb

2016-06-21 Correction

DOI: 10.1039/C6CP90156E

You might also like

Compound Q&A

What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?

4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...

74440-80-54-Amino-3-bromopheno...
Compound Q&A

How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?

(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...

1425-10-1(17beta)-3-Oxoestr-4...
Compound Q&A

What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?

2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...

76505-71-02-[(2,2-Diethoxyethy...
Compound Q&A

What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?

The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...

6736-58-91-(beta-D-Ribofurano...
Compound Q&A

How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?

Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...

12126-59-9Conjugated Estrogen
Compound Q&A

What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?

The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...

88738-78-7Bis(2,2,2-trifluoroe...
Compound Q&A

Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?

There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...

57499-59-93,4'-Di-O-methylella...
Compound Q&A

What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?

2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...

59047-70-02-Chloro-N,N-dimethy...
Compound Q&A

What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?

Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...

13597-19-8cerium(3+);oxygen(2-...
Compound Q&A

Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?

7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...

1203579-27-47-Chloro-1-iodoisoqu...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.