Experimental structure determination of the chemisorbed overlayers of chlorine and iodine on Au{111}
Literature Information
Zhasmina V. Zheleva, Vinod R. Dhanak, Georg Held
We have performed an experimental structure determination of the ordered structures of chlorine and iodine on Au{111} using low-energy electron diffraction (LEED). Despite great similarities in the structure of the underlying substrate, which shows only minor deviations from the bulk positions in both cases, chlorine and iodine are found to adsorb in different adsorption sites, fcc and hcp hollow sites, respectively. The experimental Au–Cl and Au–I bond lengths of 2.56 and 2.84 Å are close to the sums of the covalent radii, supporting the view that the bond is essentially covalent in nature; however, they are significantly shorter than predicted theoretically.
Related Literature
Analytical derivatives, π bonding and d–s mixing in the ligand field molecular mechanics method
Robert J. Deeth, David L. Foulis
DOI: 10.1039/B203815C
The structure of a zinc metaphosphate glass. A reverse Monte Carlo study
G. Navarra, A. Falqui, G. Piccaluga, G. Pinna
DOI: 10.1039/B204964C
The prediction of energies and geometries of hydrogen bonded DNA base-pairs via a topological electrostatic potential
Laurent Joubert, Paul L. A. Popelier
DOI: 10.1039/B204485D
Correlated ab initio study of nucleic acid bases and their tautomers in the gas phase, in a microhydrated environment and in aqueous solution Part 1. Cytosine
Semen A. Trygubenko, Tetyana V. Bogdan, Manuel Rueda, Modesto Orozco, F. Javier Luque, Jiří Šponer, Petr Slavíček, Pavel Hobza
DOI: 10.1039/B202156K
Vibrational predissociation of ArHF: a test of global semiempirical potential energy surfaces
Roman V. Krems, Sture Nordholm
DOI: 10.1039/B204480N
Chiral aggregates of indan-1-ol with secondary alcohols and water: Laser spectroscopy in supersonic beams
A. Paladini, M. Satta, D. Catone, S. Piccirillo, M. Speranza
DOI: 10.1039/B204909K
Gas phase reactions of C1–C4 alcohols with the OH radical: A quantum mechanical approach
Annia Galano, J. Raúl Alvarez-Idaboy, Graciela Bravo-Pérez, Ma. Esther Ruiz-Santoyo
DOI: 10.1039/B205630E
Phase transition in swollen gels Part 32. Temperature transition in charged poly(N-isopropylmethacrylamide) hydrogels in water and aqueous NaCl solutions
A. Fomenko, H. Pospíšil, Z. Sedláková, J. Pleštil
DOI: 10.1039/B203378J
Temperature dependence of isotope fractionation in N2O photolysis
Jan Kaiser, Thomas Röckmann, Carl A. M. Brenninkmeijer
DOI: 10.1039/B204837J
A calorimetric and statistical mechanics study of water adsorption in zeolite NaY
B. Boddenberg, G. U. Rakhmatkariev, S. Hufnagel, Z. Salimov
DOI: 10.1039/B203088H
You might also like
How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?
Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...
What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?
Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...
Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?
Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...
Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?
Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...
Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?
Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...
Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?
(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...
How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?
(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...
What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?
Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...
What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?
6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...
Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?
3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![4,4'-[2,5-Biphenyldiylbis(oxy)]dianiline structure 4,4'-[2,5-Biphenyldiylbis(oxy)]dianiline structure](https://static.chemtradehub.com/structs/941/94148-67-1-24c6.webp)
![4-Nitrophenyl N-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-isoleucinate structure 4-Nitrophenyl N-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-isoleucinate structure](https://static.chemtradehub.com/structs/169/16948-38-2-c88f.webp)


![2,2'-[(Abieta-8,11,13-trien-18-ylimino)bis(2,1-ethanediyloxy)]diethanol structure 2,2'-[(Abieta-8,11,13-trien-18-ylimino)bis(2,1-ethanediyloxy)]diethanol structure](https://static.chemtradehub.com/structs/513/51344-62-8-8518.webp)