Physico-chemical and structural characterization of the binary system phosphoric acid–N,N-dimethylformamide

Literature Information

Publication Date 2010-06-08
DOI 10.1039/B926140K
Impact Factor 3.676
Authors

Yuliya A. Fadeeva, Lyubov P. Safonova, Ingmar Persson


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Abstract

The binary phosphoric acid (H3PO4)–N,N-dimethylformamide (DMF) system has very different physico-chemical properties depending on composition. This paper summarizes the physico-chemical data newly collected and reported previously on the H3PO4–DMF system, and proposes structural models for the different regions of composition. The internal hydrogen bonding between pairs of phosphoric acid molecules in cyclic dimeric units is very important as well as the role of the DMF oxygen as hydrogen bond acceptor linking the dimeric phosphoric acid units into polymeric layers and three-dimensional networks.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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