Ru(iv)-catalyzed isomerization of allylamines in water: A highly efficient procedure for the deprotection of N-allylic amines

Literature Information

Publication Date 2005-07-13
DOI 10.1039/B506788J
Impact Factor 6.222
Authors

Victorio Cadierno, Sergio E. García-Garrido, José Gimeno, Noel Nebra


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Abstract

A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes [Ru(η3 ∶ η2 ∶ η3-C12H18)Cl2] (1) and [{Ru(η3 ∶ η3-C10H16)(μ-Cl)Cl}2] (2), has been developed.

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