Remote control of bipyridine–metal coordination within a peptidedendrimer

Literature Information

Publication Date 2009-09-02
DOI 10.1039/B912291E
Impact Factor 6.222
Authors

Nicolas A. Uhlich, Peter Sommer, Claudia Bühr, Stefan Schürch, Jean-Louis Reymond, Tamis Darbre


View Original

Abstract

The metal coordinating ability of a bipyridine ligand at the core of a peptide dendrimer was found to be controlled by the nature of amino acids placed at the dendrimer periphery, with coordination being promoted by anionic residues and inhibited by cationic residues; heterotrimers with mixed charges were preferentially formed.

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