Eliminating the need for independent counterions in the construction of metal–organic rotaxane frameworks (MORFs)
Literature Information
Lisa K. Knight, V. Nicholas Vukotic, Elizabeth Viljoen, Christopher B. Caputo, Stephen J. Loeb
The combination of a disulfonated-dibenzo-24crown-8 ether wheel and a dicationic 1,2-bis(pyridinium)ethane axle yields a neutral [2]pseudorotaxane which in combination with neutral metallic units such as a Cu(II)benzoate paddlewheel or Cu(I)Br unit yields one-dimensional coordination polymers (linear and bent) which are the first examples of charge neutral, metal–organic rotaxane frameworks.
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