Eliminating the need for independent counterions in the construction of metal–organic rotaxane frameworks (MORFs)

Literature Information

Publication Date 2009-08-27
DOI 10.1039/B911889F
Impact Factor 6.222
Authors

Lisa K. Knight, V. Nicholas Vukotic, Elizabeth Viljoen, Christopher B. Caputo, Stephen J. Loeb


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Abstract

The combination of a disulfonated-dibenzo-24crown-8 ether wheel and a dicationic 1,2-bis(pyridinium)ethane axle yields a neutral [2]pseudorotaxane which in combination with neutral metallic units such as a Cu(II)benzoate paddlewheel or Cu(I)Br unit yields one-dimensional coordination polymers (linear and bent) which are the first examples of charge neutral, metal–organic rotaxane frameworks.

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