Dual reactivity of a photochemically-generated cyclic enyne–allene

Literature Information

Publication Date 2009-08-14
DOI 10.1039/B911871C
Impact Factor 6.222
Authors

Alexander V. Kuzmin, Vladimir V. Popik


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Abstract

A reactive ten-membered ring enyne–allene (τ25 °C = 5–6 min) is efficiently generated (Φ300 nm = 0.57) by UV irradiation of a thermally stable precursor in which a triple bond is masked as a cyclopropenone moiety.

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