Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes
Literature Information
Peter D. Abram, David Ellis, Georgina M. Rosair, Alan J. Welch
Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage.
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