Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Literature Information

Publication Date 2009-08-14
DOI 10.1039/B911350A
Impact Factor 6.222
Authors

Peter D. Abram, David Ellis, Georgina M. Rosair, Alan J. Welch


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Abstract

Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage.

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