Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters‡

Literature Information

Publication Date 2009-09-02
DOI 10.1039/B910465H
Impact Factor 6.222
Authors

Ahmad Masarwa, Alois Fürstner, Ilan Marek


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Abstract

Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

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