A facile iodide-controlled fluorescent switch based on the interconversion between two- and three-coordinate copper(i) complexes

Literature Information

Publication Date 2009-10-05
DOI 10.1039/B908765F
Impact Factor 6.222
Authors

Chang-Chuan Chou, Hsueh-Ju Liu, Lucas Hung-Chieh Chao


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Abstract

The first paradigm of halide-controlled interconversion between two- and three-coordinate copper(I) complexes, [Cu(LPh)](ClO4) (1·ClO4) and [Cu(LPh)I] (2), where LPh = 1,3-bis-(3,5-dimethyl-pyrazol-1-ylmethyl)-2-phenyl-2,3-dihydro-1H-perimidine, was presented, which can result in reversible fluorescence changes.

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