Reversible lithium storage in LiF/Ti nanocomposites

Literature Information

Publication Date 2009-08-20
DOI 10.1039/B908149F
Impact Factor 3.676
Authors

X. Q. Yu, J. P. Sun, K. Tang, H. Li, X. J. Huang, L. Dupont, J. Maier


View Original

Abstract

Storage and transport behaviors of lithium in LiF/Ti nanocomposites, either formed in situ through a conversion reaction from TiF3 powder electrode or prepared by the pulse laser deposition method, have been investigated. Reversible lithium storage in the LiF/Ti nanocomposites shows a sloped voltage profile. The lithium storage capacity in the LiF/Ti nanocomposite thin film is much higher than that in single Ti or LiF thin film with the same thickness and is increased with increasing film thickness. Accordingly, lithium should store at the grain boundary regions since either the LiF or the Ti phase is not active for lithium storage. Hence, this type of interfacial storage is intermediate between the insertion and storage in supercapacitors. The transport properties of electrons and lithium ions in initial LiF/Ti nanocomposites are also investigated by IV, IS and blocking electrode techniques.

Related Literature

Towards a formal definition of static and dynamic electronic correlations

Carlos L. Benavides-Riveros, Nektarios N. Lathiotakis, Miguel A. L. Marques

2017-05-05 Paper

DOI: 10.1039/C7CP01137G

Back-exchange: a novel approach to quantifying oxygen diffusion and surface exchange in ambient atmospheres

Samuel J. Cooper, Mathew Niania, Franca Hoffmann, John A. Kilner

2017-04-27 Paper

DOI: 10.1039/C7CP01317E

Single-layer MoS2 formation by sulfidation of molybdenum oxides in different oxidation states on Au(111)

Norberto Salazar, Igor Beinik, Jeppe V. Lauritsen

2017-04-20 Paper

DOI: 10.1039/C7CP00958E

Study of antiradical mechanisms with dihydroxybenzenes using reaction force and reaction electronic flux

Cristina Ortega-Moo, Rocio Durán, Bárbara Herrera, Soledad Gutiérrez-Oliva, Rubicelia Vargas

2017-05-08 Paper

DOI: 10.1039/C7CP01304C

New insights into the chemistry of ionic alkylorganic carbonates: a computational study

Khaleel I. Assaf, Abdussalam K. Qaroush, Ala'a F. Eftaiha

2017-05-17 Paper

DOI: 10.1039/C7CP02087B

Dielectric functions and critical points of crystalline WS2 ultrathin films with tunable thickness

Da-Hai Li, Hua Zheng, Zi-Yi Wang, Rong-Jun Zhang, Hao Zhang, Yu-Xiang Zheng, Song-You Wang, David Wei Zhang, Liang-Yao Chen

2017-04-12 Paper

DOI: 10.1039/C7CP00660H

Contents list

Front/Back Matter

DOI: 10.1039/C7CP90121F

Electrode potential dependent desolvation and resolvation of germanium(100) in contact with aqueous perchlorate electrolytes

Fang Niu, Rainer Schulz, Arcesio Castañeda Medina, Rochus Schmid

2017-05-10 Paper

DOI: 10.1039/C6CP08908A

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.