Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene
Literature Information
Dietrich Gudat, Timo Gans-Eichler, Martin Nieger
2-Chloro-1,3,2-diazastibolenes react with Lewis acids either via Sb–Cl cleavage to yield stable Sb-analogues of an N-heterocyclic carbene, or via an unprecedented oxidative fragmentation to give a diazadiene–SbCl3 complex.
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![(1R,5R)-3-{[(2-Methyl-2-propanyl)oxy]carbonyl}-3-azabicyclo[3.1.0]hexane-1-carboxylic acid structure (1R,5R)-3-{[(2-Methyl-2-propanyl)oxy]carbonyl}-3-azabicyclo[3.1.0]hexane-1-carboxylic acid structure](https://static.chemtradehub.com/structs/116/1165450-63-4-bfe1.webp)

