Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene

Literature Information

Publication Date 2004-09-22
DOI 10.1039/B409657F
Impact Factor 6.222
Authors

Dietrich Gudat, Timo Gans-Eichler, Martin Nieger


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Abstract

2-Chloro-1,3,2-diazastibolenes react with Lewis acids either via Sb–Cl cleavage to yield stable Sb-analogues of an N-heterocyclic carbene, or via an unprecedented oxidative fragmentation to give a diazadiene–SbCl3 complex.

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