Ion beam degradation analysis of poly(3-hexylthiophene) (P3HT): can cryo-FIB minimize irradiation damage?

Literature Information

Publication Date 2009-04-02
DOI 10.1039/B816893H
Impact Factor 3.676
Authors

Meltem Sezen, Harald Plank, Philipp M. Nellen, Stephan Meier, Boril Chernev, Werner Grogger, Evelin Fisslthaler, Emil J. W. List, Ullrich Scherf, Peter Poelt


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Abstract

In this study, to assess the influence of the temperature on the ion beam degradation, irradiation experiments on organic semiconductor materials were performed for both cryogenic and room temperature conditions. Thin P3HT films on silicon substrates were exposed to increasing ion doses in dual beam FIB. The degradation behaviour by means of a decrease in the CC band which corresponds to a loss of conjugation was investigated by means of Raman spectroscopy. In addition, atomic force microscopy (AFM) and Kelvin probe force microscopy (KPFM) were used for a characterization of morphology and surface potential which provide information on temperature and ion dose dependent degradation behaviour.

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