Absolute helicity induction in three-dimensional homochiral frameworks
Literature Information
Jian Zhang, Xianhui Bu
Three Co(II) isomers assembled from D-, or L-, or DL-camphorate together with achiral isonicotinate exhibit a clear relationship between chirality and helicity even though chiral molecules are not in the backbone of the helix: the absolute sense of helix made of achiral components is controlled by chains of metal and enantiopure chiral ligands running perpendicular to helix in two enantiomeric forms.
Related Literature
The British Pharmaceutical Codex, 1934. Fourth supplement: Part I, monographs (amendments)
DOI: 10.1039/AN942670265C
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