Photovoltaic activity of layered zirconium phosphates containing covalently grafted ruthenium tris(bipyridyl) and diquat phosphonates as electron donor/acceptor sites
Literature Information
Laura Teruel, Marina Alonso, M. Carmen Quintana, Álvaro Salvador, Olga Juanes, Juan Carlos Rodriguez-Ubis, Ernesto Brunet, Hermenegildo García
Two layered zirconium phosphates containing Ru(bpy)32+ mono- or diphosphonates and diquat, {Ru(bpy)32+[1]/ZrP/DQ++} and Ru(bpy)32+[2]/ZrP/DQ++, covalently attached to the phosphate layers exhibit notable photovoltaic response (the maximum VOC, JSC, and FF were 0.093 V, 16.8 μA cm−2 and 0.33, respectively). The photocurrent spectra indicate that the photovoltaic response is due predominantly to direct photoexcitation of γ-ZrP host, Ru(bpy)32+ and diquat acting as hole and electron traps, respectively, for the charge separated state of the semiconductor.
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