Formation of a stannylstannylenevia intramolecular carbene addition of a transient stannaacetylene (RSnCR′)
Literature Information
Katsuyuki Hirai, Hideo Tomioka, Kenkichi Sakamoto, Mitsuo Kira
Photolysis of diazomethylstannylene [1, Me3SiC(N2)(Ar)Sn:, Ar = C6H3-2,6-Tip2, Tip = C6H2-2,4,6-(i-Pr)3] afforded unusual stannylstannylene 3via intramolecular carbene addition to an aromatic π bond of stannaacetylene 2; the structures of compounds 1 and 3 were fully characterized by X-ray crystallography.
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