Enhancement of H2adsorption in Li+-exchanged co-ordination framework materials

Literature Information

Publication Date 2008-10-14
DOI 10.1039/B814155J
Impact Factor 6.222
Authors

Sihai Yang, Xiang Lin, Alexander J. Blake, K. Mark Thomas, Peter Hubberstey, Neil R. Champness, Martin Schröder


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Abstract

H2 adsorption in (Me2NH2)[In(L)] is enhanced by exchange of Me2NH2+ for Li+ cations; the Li+-exchanged material displays a lower isosteric heat for H2 adsorption than the parent material, indicating that the increase in H2 capacity is due to an increase in the accessible pore volume on cation exchange, while the lower adsorption enthalpy is consistent with increased pore size.

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