![2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure](https://static.chemtradehub.com/structs/877/877395-58-9-70bf.webp "2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure")
2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol
CAS Number:
877395-58-9
Molecular Formula:
C43H46N2O3
Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloadditionversus C–H bond activation
Literature Information
Publication Date
2008-09-18
DOI
10.1039/B811952J
Impact Factor
6.222
Authors
Shenglai Yao, Christoph van Wüllen, Matthias Driess
View Original
Abstract
The isolable ylide-like N-heterocyclic germylene LGe: (2) {L = CH[(CCH2)CMe][N(aryl)]2, aryl = 2,6-iPr2C6H3} shows an unprecedented dual reactivity toward terminal alkynes: its reaction with acetylene leads via[4+2] cycloaddition to the novel intramolecular donor stabilised germylene 3, while conversion of phenylacetylene furnishes the analogous cycloadduct 4 along with a C–H bond activation product, the novel N-donor stabilised alkynyl germylene 5.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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